Trimethylsilyl chloride assisted conjugate addition-elimination of organocopper reagents to 2-bis(methylthio)nitroethylene: An efficient and highly stereoselective synthesis of 2-methylthio-2-alkyl/aryl-1- nitroethylenes and their application for synthesi

DOI: 10.1016/S0040-4020(98)00790-X

Source and publish data:

Tetrahedron p. 12973 - 12984 (1998)

Update date:2022-08-02

Topics:

Authors:

Terang, Nobin

Mehta, Barun K.

Ila Ila

Junjappa

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Article abstract of DOI:10.1016/S0040-4020(98)00790-X

An efficient method for the synthesis of novel 2-methylthio-2- alkyl/aryl-1-nitroethylenes 2 has been developed via conjugate addition- elimination of organocopper reagents to nitroketene dithioacetal 1 in the presence of TMSCI. The product nitroethylenes

Full text of DOI:10.1016/S0040-4020(98)00790-X

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