Carbamoyl radicals from se-phenylselenocarbamates: Intramolecular additions to alkenes

DOI: 10.1016/S0040-4039(98)01830-9

Source and publish data:

Tetrahedron Letters p. 8413 - 8416 (1998)

Update date:2022-09-26

Topics: alkenes intramolecular addition

Authors:

Rigby, James H.

Danca, Diana M.

Horner, John H.

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Article abstract of DOI:10.1016/S0040-4039(98)01830-9

A series of 5 exo-trig cyclizations of carbamoyl radicals generated from readily available Se-phenylselenocarbamates is reported. Kinetic studies indicate that the rate constant of this cyclization exceeds 1 x t 0⁸s^-1 in several cases.

Full text of DOI:10.1016/S0040-4039(98)01830-9

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