STEREOSELECTIVE TOTAL SYNTHESES OF (+/-)- AND OPTICALLY ACTIVE DEHYDROIRIDODIOLS

DOI: 10.1246/cl.1983.147

Source and publish data:

Chemistry Letters p. 147 - 148 (1983)

Update date:2022-09-26

Topics:

Authors:

Nakayama, Mitsuru

Ohira, Susumu

Takata, Seishi

Fukuda, Kenzo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1983.147

(+/-)-Dehydroiridodiol and its epimer (+/-)-isodehydroiridodiol were synthesized stereoselectively using the homoconjugate addition of cyanide anion to methyl 6-methyl-2-oxobicyclo<3.1.0>hexane-1-carboxylates.Both enantiomers of dehydroiridodiol were prepared after the resolution of l-menthyl 6-methyl-2-oxobicyclo<3.1.0>hexane-1-carboxylate, whose absolute configurations became clear as the result.

Full text of DOI:10.1246/cl.1983.147

Products guided by the article

Product name:isodehydroiridodiol (3R^*,8R^*)

Cas No:21700-67-4

R&D Labs maybe for 21700-67-4

Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China

Relevant to this article

Doi:10.1007/BF00760285
()
Doi:10.1007/BF01154348
(1968)
The Synthesis of Naturally Occurring C6-C3 and C6-C3-C6 Substances by the Use of Low-Valent Nickel-Mediated Grignard Reactions

Doi:10.1055/s-1983-30474
(1983)
Efficient intramolecular hydroalkoxylation of unactivated alkenols mediated by recyclable lanthanide lriflate ionic liquids: Scope and mechanism

Doi:10.1002/chem.200902269
(2010)
Synthesis and biological characterization of L-N⁶-(1-iminoethyl)lysine 5-tetrazole-amide, a prodrug of a selective iNOS inhibitor

Doi:10.1021/jm010420e
(2002)
Analogs of 4-(3-bromo-8-methyl-10-methoxy-6,11-dihydro-5H- benzo[5,6]cyclohepta[1,2-b]pyridin-11-yl)-1-(4-pyridinylacetyl)piperidine N- oxide as inhibitors of farnesyl protein transferase

Doi:10.1016/S0960-894X(99)00287-5
(1999)

Article Doi