STEREOSELECTIVE TOTAL SYNTHESES OF (+/-)- AND OPTICALLY ACTIVE DEHYDROIRIDODIOLS

DOI: 10.1246/cl.1983.147

Source and publish data:

Chemistry Letters p. 147 - 148 (1983)

Update date:2022-09-26

Topics:

Authors:

Nakayama, Mitsuru

Ohira, Susumu

Takata, Seishi

Fukuda, Kenzo

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Article abstract of DOI:10.1246/cl.1983.147

(+/-)-Dehydroiridodiol and its epimer (+/-)-isodehydroiridodiol were synthesized stereoselectively using the homoconjugate addition of cyanide anion to methyl 6-methyl-2-oxobicyclo<3.1.0>hexane-1-carboxylates.Both enantiomers of dehydroiridodiol were prepared after the resolution of l-menthyl 6-methyl-2-oxobicyclo<3.1.0>hexane-1-carboxylate, whose absolute configurations became clear as the result.

Full text of DOI:10.1246/cl.1983.147

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