Chemistry Letters p. 147 - 148 (1983)
Update date:2022-09-26
Topics:
Nakayama, Mitsuru
Ohira, Susumu
Takata, Seishi
Fukuda, Kenzo
(+/-)-Dehydroiridodiol and its epimer (+/-)-isodehydroiridodiol were synthesized stereoselectively using the homoconjugate addition of cyanide anion to methyl 6-methyl-2-oxobicyclo<3.1.0>hexane-1-carboxylates.Both enantiomers of dehydroiridodiol were prepared after the resolution of l-menthyl 6-methyl-2-oxobicyclo<3.1.0>hexane-1-carboxylate, whose absolute configurations became clear as the result.
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Doi:10.1007/BF00760285
()Doi:10.1007/BF01154348
(1968)Doi:10.1055/s-1983-30474
(1983)Doi:10.1002/chem.200902269
(2010)Doi:10.1021/jm010420e
(2002)Doi:10.1016/S0960-894X(99)00287-5
(1999)
