Photochemical rearrangement of 2-phenylthio-3-aminocyclohexanols. New access to deoxyazasugars and their derivatives

Article abstract of DOI:10.1016/S0040-4039(98)01796-1

This paper reports the regioselective photorearrangement of 2- phenylthio-3-aminocyclohexanols to deoxyazasugars and their derivatives. These give access to variously substituted piperidines, amino-sulfones, - sulfoxides and -acids.