A short synthesis of the bicyclic core of the zaragozic acids

DOI: 10.1016/S0040-4039(98)01726-2

Source and publish data:

Tetrahedron Letters p. 7853 - 7856 (1998)

Update date:2022-08-03

Topics:

Authors:

Fraisse, Pierre

Hanna, Issam

Lallemand, Jean-Yves

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Article abstract of DOI:10.1016/S0040-4039(98)01726-2

A synthesis of the highly functionalized bicyclic core of the zaragozic acids is described, in which the key step involves the construction of the C4 quaternary carbon center by a CeCl₃-promoted aldol reaction between the α- D-xylofuranuronic acid derivative 2 and D-(R)-glyceraldehyde acetonide.

Full text of DOI:10.1016/S0040-4039(98)01726-2

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