On 1,4-diastereoselectivity in the chiral allylsilane addition to chiral α-substituted aldehydes

DOI: 10.1016/S0040-4039(98)01066-1

Source and publish data:

Tetrahedron Letters p. 5343 - 5346 (1998)

Update date:2022-09-26

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Authors:

Dias, Luiz C.

Giacomini, Rosana

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Article abstract of DOI:10.1016/S0040-4039(98)01066-1

Chiral allyisilane 2 reacted with chiral α-substituted aldehydes to afford the corresponding 1,4-syn-products with good diastereoseletivities. The best selectivities are observe when the reactions are carried out by transmetallation of allylsilane using T

Full text of DOI:10.1016/S0040-4039(98)01066-1

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