On 1,4-diastereoselectivity in the chiral allylsilane addition to chiral α-substituted aldehydes

DOI: 10.1016/S0040-4039(98)01066-1

Source and publish data:

Tetrahedron Letters p. 5343 - 5346 (1998)

Update date:2022-09-26

Topics:

Authors:

Dias, Luiz C.

Giacomini, Rosana

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)01066-1

Chiral allyisilane 2 reacted with chiral α-substituted aldehydes to afford the corresponding 1,4-syn-products with good diastereoseletivities. The best selectivities are observe when the reactions are carried out by transmetallation of allylsilane using T

Full text of DOI:10.1016/S0040-4039(98)01066-1

Products guided by the article

Product name:[(2R,5R,6R)-7-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-3-methylene-5-trimethylsilanyloxy-heptyloxymethyl]-benzene

Cas No:217964-67-5

R&D Labs maybe for 217964-67-5

uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.

Contact:+86-576-87501888 / 87501988

Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian
Changzhou Sunsheng Chem Co., Ltd

Contact:+1-(989)-854-0648

Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
zhenjiang runjing high purity chemical co ltd

Contact:+86-511-83361155

Address:No.8.haixi road,international chemical park

Relevant to this article

Doi:10.1002/jlcr.2590050109
(1969)
The synthesis of the vitamers of biotin

Doi:10.1006/bioo.1998.1094
(1998)
Doi:10.1016/S0040-4039(01)87743-1
(1969)
Stereoselective assembly of a 1,3-diene via coupling between an allenic acetate and a (B)-alkylborane: Synthetic studies on amphidinolide B1

Doi:10.1021/ol051175m
(2005)
Pd-catalyzed synthesis of a tethered soluble polymeric phosphine ligand

Doi:10.1016/S0040-4039(98)01976-5
(1998)
Nitrogen - Carbon-linked (azolylphenyl) oxazolidinones with potent antibacterial activity against the fastidious gram-negative organisms Haemophilus influenzae and Moraxella catarrhalis [1]

Doi:10.1021/jm980546k
(1998)

Article Doi