Coordination compounds of bismuth. Bismuth(III) derivatives of di(o-aminophenyl)disulfide and di(p-tolyl)disulfide

Article abstract of DOI:10.1080/00945719809349419

Bismuth metal reacts with di(o-aminophenyl)disulfide (o-H₂NC₆H₄S)₂ and di(p-tolyl)disulfide (p-MeC₆H₄S)₂ in refluxing toluene to give the compounds Bi(SC₆H₄NH₂-o)₃ and Bi(SC₆H₄Me-p)₃ in high yield. The reaction of bismuth with a mixture of iodine and (o-H₂NC₆H₄S)₂ or (p-Me-C₆H₄S)₂ gives the compounds BiI(SC₆H₄NH₂-o)₂, BiI(SC₆H₄Me-p)₂, BiI₂(SC₆H₄NH₂-o) and BiI₂(SC₆H₄Me-p)₂. Adducts of some of the above compounds with 1,10-phenanthroline and 2,2'-bipyridyl were also prepared. The compounds and adducts were characterised by microanalyses, infrared, UV/Visible spectroscopy and conductivity measurements.

Full text of DOI:10.1080/00945719809349419

This article was downloaded by: [Florida Atlantic University]
On: 18 November 2014, At: 00:26
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsrt19
Coordination Compounds
of Bismuth. Bismuth(III)
Derivatives of Di(o-
Aminophenyl)Disulfide and
Diw-Tolyl)Disulfide
N. H. Buttrus a
a Chemistry Department, College of Science ,
University of Mosul , Mosul, Iraq
Published online: 14 Apr 2008.
To cite this article: N. H. Buttrus (1998) Coordination Compounds of Bismuth.
Bismuth(III) Derivatives of Di(o-Aminophenyl)Disulfide and Diw-Tolyl)Disulfide,
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 28:10, 1643-1652,
DOI: 10.1080/00945719809349419
To link to this article: http://dx.doi.org/10.1080/00945719809349419
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any

losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions