Inorganic Chemistry p. 1120 - 1125 (1963)
Update date:2022-08-04
Topics:
Grafstein, Daniel
Bobinski, Jack
Dvorak, Joseph
Smith, Harry
Schwartz, Nelson
Cohen, Murray S.
Fein, Marvin M.
The reactions of the carboranyl polyhedron and its influence on the chemistry of organofunctional substituents were investigated. Convenient laboratory syntheses for carborane, 1-methylcarborane, and some functional derivatives were developed. An unusual rearrangement in a Grignard reagent was observed. Metalation, animation, solvolytic degradation, and other reactions of these novel compounds were studied.
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