Erythrulose as a multifunctional chiron: Highly stereoselective boron aldol additions

DOI: 10.1016/S0040-4039(99)80113-0

Source and publish data:

Tetrahedron Letters p. 1065 - 1068 (1999)

Update date:2022-09-26

Topics:

Authors:

Marco, J. Alberto

Carda, Miguel

Falomir, Eva

Palomo, Claudio

Oiarbide, Mikel

Ortiz, J. Aurelio

Linden, Anthony

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Article abstract of DOI:10.1016/S0040-4039(99)80113-0

We have investigated the formation of various metal enolates of 1-O- silylated erythrulose 3,4-acetonides. We were able to prepare boron enolates using Brown's dicyclohexylboron chloride / tertiary amine system. When these enolates were allowed to react w

Full text of DOI:10.1016/S0040-4039(99)80113-0

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