Reversible Displacement of Polyagostic Interactions in 16e Mn(CO)(R2PC2H4PR2)2} by H2,N2, and so2. Binding and Activation of η2-H2 trans to CO Is Nearly Invariant to C

Article abstract of DOI:10.1021/ic981263l

Electrophilic l6e [Mn(CO)(R₂PC₂}LPR₂)₂]⁺ complexes (R = Et, Ph) are synthesized by metathesis of MnBr-(CO)(R₂PC₂H₄PR₂)₂ with Na or Li salts of lo