Remarkable catalytic activity of Me3Ga in the alkylation of hetero- substituted epoxides with alkynyllithiums

DOI: 10.1016/S0040-4039(99)01096-5

Source and publish data:

Tetrahedron Letters p. 5881 - 5884 (1999)

Update date:2022-09-26

Topics:

Authors:

Ooi, Takashi

Morikawa, Junko

Ichikawa, Hayato

Maruoka, Keiji

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Article abstract of DOI:10.1016/S0040-4039(99)01096-5

Regio- and stereoselective ring-opening reaction of hetero-substituted epoxides with alkynyllithiums can be catalyzed by Me₃Ga with remarkable efficiency at 0-20°C via pentacoordinate chelate-type complex.

Full text of DOI:10.1016/S0040-4039(99)01096-5

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