Tetrahedron Letters p. 1911 - 1914 (1999)
Update date:2022-08-03
Topics:
Saeeng
Isobe
An ABC segment of ciguatoxin has been synthesized in a correct enantiomeric form from a D-glucose derivative based on the route for the opposite enantiomer by switching enantiomerism of a pseudosymmetric intermediate. This route, however, has been improved in several steps and ended up with a vinylthioether group for future extension toward the D ring of ciguatoxin molecule.
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(1999)Doi:10.1016/S0040-4020(02)01258-9
(2003)Doi:10.1016/S0957-4166(99)00018-X
(1999)Doi:10.1002/jlac.19697230117
(1969)Doi:10.1021/jm061043e
(2007)
