Heterocycles p. 727 - 731 (1999)
Update date:2022-08-04
Topics:
Ozaki, Yutaka
Quan, Zhe-Shan
Watabe, Kyouko
Kim, Sang-Won
1,4-Cyclohexanedione reacted with 2-oxocarboxylic acids to give 5- hydroxyoxaindan-2-ones including homogentisic lactone in one pot. The obtained aromatic compounds were transformed into indol-5-ols in a few steps. The sequential reactions showed a significance of 1,4-cyclohexanedione as a starting material in aromatic synthesis and an alternative access to the indol-5-ols.
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Doi:10.1021/acs.joc.8b02706
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