Organic and Biomolecular Chemistry p. 7549 - 7553 (2020)
Update date:2022-07-29
Topics:
Du, Ding
Feng, Jie
Ma, Rui
Zhang, Beichen
Zhang, Kuili
An olefinic difunctionalization method of enones was presented hereviaaerobic visible-light catalysis. A novel reactivity was showcased in conjunction with the selective Csp2-C(CO) bond activation of enones, which provided a convenient method for the preparation of various β-thiolated-α-functionalized compounds. Moreover, the preliminary investigation of the mechanism indicated that a β-peroxysulfide intermediate was formed under the promotion of visible light under an oxygen atmosphere, which finally induced the unexpected C-C bond cleavage.
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