Participation of the chiral sulfinyl functionality in palladium- catalyzed asymmetric vinylcyclopropane-cyclopentene rearrangements

DOI: 10.1016/S0040-4039(99)00508-0

Source and publish data:

Tetrahedron Letters p. 3431 - 3434 (1999)

Update date:2022-07-30

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Authors:

Hiroi, Kunio

Yoshida, Yasuki

Kaneko, Yoko

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Article abstract of DOI:10.1016/S0040-4039(99)00508-0

Stereochemical studies on the palladium-catalyzed asymmetric 1,3- rearrangements of [4-chiral arylsulfinyl-1,3(E or Z)- butadienyl]cyclopropanes to chiral cyclopentenes are described. The plausible mechanism for the rationalization of the stereochemical outcomes is proposed.

Full text of DOI:10.1016/S0040-4039(99)00508-0

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