Regioselectivity of the Alkylation of Ambident Anionic Species on Alumina or in the Presence of 'Solid Hexamethylphosphoric Triamide'

DOI: 10.1039/c39800000325

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 325 - 326 (1980)

Update date:2022-08-04

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Authors:

Bram, Georges

Geraghty, Niall

Nee, Gerard

Seyden-Penne, Jacqueline

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Article abstract of DOI:10.1039/c39800000325

C-Alkylation of the acetoacetate anions and of sodium naphthoxide is highly favoured on alumina, while O-alkylation of the acetoacetate anion predominates in tetrahydrofuran in the presence of solid hexamethylphosphoric triamide.

Full text of DOI:10.1039/c39800000325

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