Tetrahedron p. 3329 - 3335 (2012)
Update date:2022-08-02
Topics:
Tongkate, Pratoomrat
Phromyothin, Darinee
Sumranjit, Jitapa
Oligo-phenylene vinylene (oligo-PV) with two picolinamide side-groups and six methoxy end-groups was synthesized in order to be a fluorescent sensing molecule. Various metal ion solutions (1.5×10-4 M) were added to the 1.5×10-6 M acetonitrile solution of the fluorescent molecule. The fluorescent emission spectra showed that, at about the same concentration (1.5×10-4 M), only Cu(II) ion can quench the fluorescent emission of the picolinamide-PV solution. Possible metal ion-sensing mechanisms could be either the binding at picolinamide side-groups or methoxy end-groups, or interchain-stacking driven by the metal ions. Hence, oligo-PVs with six methoxy end-groups but without substituted side-groups, and another oligo-PV with six methoxy end-groups and two ethoxy side-groups were synthesized for comparison. These molecules turned out to be inactive to any metal ion solutions. Moreover, quantum calculation was used to confirm the result. Binding energy and conformation were calculated and simulated. It could be concluded that nitrogen and oxygen atoms of the picolinamide group and one oxygen atom from the methoxy group are involved in the metal ion-binding process.
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