Synthesis and crystal structure of bis(triphenylphosphine)gold tricyanomethanide, +-

DOI: 10.1016/0022-328X(89)87238-9

Source and publish data:

Journal of Organometallic Chemistry p. 465 - 471 (1989)

Update date:2022-08-02

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Authors:

Naukova, T. V.

Kravtsov, D. N.

Kuz'mina, L. G.

Dvortsova, N. V.

Poray-Koshits, M. A.

Perevalova, E. G.

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Article abstract of DOI:10.1016/0022-328X(89)87238-9

A new unusual transformation of tetracyanoethylene (TCE) into a tricyanomethanide anion ^- has been found.This transformation occurs as a result of action of tris(triphenylphosphinegold)oxonium tetrafluoroborate ⁺B

Full text of DOI:10.1016/0022-328X(89)87238-9

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Product name:Au⁽¹⁺⁾*CN^(1-)*P(C₆H₅)3=AuCN*P(C₆H₅)3

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