Tetrahedron Letters p. 5101 - 5104 (1999)
Update date:2022-08-03
Topics:
Moss, Robert A.
Wei, Ma
Diphenylmethylchlorocarbene (5) exhibits minimal 1,2-Ph migration (k(Ph)=1.5x106 s-1); 1,2-H migration (k(H)=2.1x107 s-1) is 14 times faster in pentane at 25°C.
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