First synthesis of (±)-10β-hydroxy-13β methylcyclohexa[a]quinolizidine. A convenient route to the ABC-part of 8- azasteroids

DOI: 10.1016/S0040-4020(99)00497-4

Source and publish data:

Tetrahedron p. 9269 - 9282 (1999)

Update date:2022-08-04

Topics:

Authors:

Celanire, Sylvain

Salliot-Maire, Isabelle

Ribereau, Pierre

Godard, Alain

Queguiner, Guy

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Article abstract of DOI:10.1016/S0040-4020(99)00497-4

The first synthesis of racemic 10β-hydroxy-13β- methylcyclohexa[a]quinolizidine is reported. Original construction of AC- bicyclic system is achieved by lateral metallation of 2-ethylpyridine followed by a Robinson annelation, with the creation of a quate

Full text of DOI:10.1016/S0040-4020(99)00497-4

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