
Tetrahedron Letters p. 6117 - 6120 (1999)
Update date:2022-08-04
Topics:
Fagan, Maria A.
Knight, David W.
5-Endo-dig iodocyclisation of the homopropargylic sulfonamide 10 gives the iodo-dihydropyrrole 11; subsequent 5-exo-trig radical cyclisation of the derived iodopyrrole 12 followed by allylic oxidation then delivers the bicyclic core 2 of Roseophilin 1.
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