A new approach to the core of Roseophilin

DOI: 10.1016/S0040-4039(99)01217-4

Source and publish data:

Tetrahedron Letters p. 6117 - 6120 (1999)

Update date:2022-08-04

Topics:

Authors:

Fagan, Maria A.

Knight, David W.

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Article abstract of DOI:10.1016/S0040-4039(99)01217-4

5-Endo-dig iodocyclisation of the homopropargylic sulfonamide 10 gives the iodo-dihydropyrrole 11; subsequent 5-exo-trig radical cyclisation of the derived iodopyrrole 12 followed by allylic oxidation then delivers the bicyclic core 2 of Roseophilin 1.

Full text of DOI:10.1016/S0040-4039(99)01217-4

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