Journal of Organometallic Chemistry p. 201 - 210 (1981)
Update date:2022-08-03
Topics:
Firgo, Heinrich A.
Weber, William P.
The zinc chloride-catalyzed reaction of oxetane with methylthiotrimethylsilane yields (3-chloropropoxy)trimethylsilane (minor) and (3-methylthiopropoxy)trimethylsilane (major).Similar results have been obtained with 2-methyloxetane, 3,3-dimethyloxetane and 2,2-dimethyloxetane.These results have been interpreted in terms of competing SN1 and SN2 processes.
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