Selective cleavage of the trisubstituted cyclopropanes via cyclopropylcarbinyl radical fragmentation

DOI: 10.1016/S0040-4039(99)01366-0

Source and publish data:

Tetrahedron Letters p. 6817 - 6820 (1999)

Update date:2022-08-03

Topics:

Authors:

Takekawa, Yuki

Shishido, Kozo

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Article abstract of DOI:10.1016/S0040-4039(99)01366-0

The fragmentation reaction of the optically pure 2-aryl-3-alkylcyclopropylcarbinyl radicals 1 proceeded selectively to generate a benzyl radical and produce the optically pure 4-aryl-3-alkyl-1-butenes 2, which can serve as synthetically useful chiral buil

Full text of DOI:10.1016/S0040-4039(99)01366-0

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