Tetrahedron Letters p. 4901 - 4904 (1989)
Update date:2022-08-02
Topics:
Bainbridge, Kathleen E.
Dailey, William P.
Treatment of isotopically labeled bromophenyldiazirine containing one 15N atom with azide ion produces benzonitrile which contains 50percent 15N.This suggests that N-azidodiazirines are intermediates in the reaction.Ab initio calculations predict that N-azidodiazirines will have a very low barrier to decomposition to nitrile and two molecules of nitrogen.
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