Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2396 - 2412 (1980)
Update date:2022-08-04
Topics:
Baldwin, Roy R.
Bennett, Joan P.
Walker, Raymond W.
A detailed analysis has been made of the products formed when 1percent of pent-1-ene and of cis-pent-2-ene are added to slowly reacting mixtures of H2 + O2 in aged boric-acid-coated vessels at 480 deg C.The primary products are formed through four different types of attack on the pentenes of almost equal importance, radical addition of H, OH, and HO2, and H atom abstraction from the pentenes by all three radicals.Penta-1,3-diene is the only C5 diene observed, in marked contrast to an earlier study of pentene oxidation.From measurements of the initial relative yields of penta-1,3-diene and buta-1,3-diene, a value of k2 = 2.1 x 1E6 dm3 mol-1 s-1 at 480 deg C is obtained.
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