[N-Acetyl-N′-methylureato(2-)-N,N′](η 5-pentamethylcyclopentadienyl)(triphenyl-phosphine-P)iridium(III) chloroform solvate

DOI: 10.1107/S0108270199007581

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 1778 - 1780 (1999)

Update date:2022-08-03

Topics:

Authors:

Dinger, Maarten B.

Henderson, William

Oliver, Allen G.

Rickard, Clifton E. F.

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Article abstract of DOI:10.1107/S0108270199007581

The title complex, [Ir(C₁₀H₁₅)(C₄H₆N₂O ₂)(C₁₈H₁₅P)]-CHCl₃, displays a 'piano-stool'-type configuration of ligands, with the Ir atom in an Ir-NR-C(O)-NR′ ring system. This is the first structure determination of a coordinatively saturated iridaureylene complex.

Full text of DOI:10.1107/S0108270199007581

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