[N-Acetyl-N′-methylureato(2-)-N,N′](η 5-pentamethylcyclopentadienyl)(triphenyl-phosphine-P)iridium(III) chloroform solvate

Article abstract of DOI:10.1107/S0108270199007581

The title complex, [Ir(C₁₀H₁₅)(C₄H₆N₂O ₂)(C₁₈H₁₅P)]-CHCl₃, displays a 'piano-stool'-type configuration of ligands, with the Ir atom in an Ir-NR-C(O)-NR′ ring system. This is the first structure determination of a coordinatively saturated iridaureylene complex.