
Tetrahedron Letters p. 8059 - 8062 (1999)
Update date:2022-07-31
Topics:
Zaim, Oemer
Treatment of allylic alcohols with thiophosgene and pyridine gives thiolo chloroformates directly at room temperature, presumably via very rapid [3,3] sigmatropic rearrangements of thiono chloroformates. Synthesis of allyl thiono chloroformate from allyl alcohol, sodium hydride and thiophosgene at low temperature and warming up to room temperature supports this finding.
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