
Tetrahedron Letters p. 4859 - 4862 (1991)
Update date:2022-08-05
Topics:
Smith III, Amos B.
Salvatore, Brian A.
Hull, Kenneth G.
Duan, James J.-W.
The C(9)-C(13) dithiane (+)-2 and C(26)-C(37) γ-amino acid/oxazole (+)-5, key building blocks for calyculin total synthesis, have been elaborated in homochiral form. Noteworthy features of the schemes include stereocontrolled generation of the C(36) steeo
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