Pentafluorophenylation of Aromatics with Pentafluorophenyl Perfluoro- and Polyfluoroalkanesulfonates. A Photoinduced Electron-Transfer Cation Diradical Coupling Process

DOI: 10.1021/jo00061a041

Source and publish data:

Journal of Organic Chemistry p. 2599 - 2604 (1993)

Update date:2022-08-03

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Authors:

Chen, Qing-Yun

Li, Zhan-Ting

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Article abstract of DOI:10.1021/jo00061a041

Irradiation of pentafluorophenyl perfluoro- and polyfluoroalkanesulfonates 1 with arenes, aromatic ethers, pyrroles, indoles, and phenols results in the corresponding pentafluorophenylated aromatic compounds.An electron-transfer mechanism is proposed.

Full text of DOI:10.1021/jo00061a041

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