Reactivity of acryloyl chloride towards the anion [Cp2(CO)4Mo2(μ- PPhH)]-; synthesis of an unusual phosphaalkene

DOI: 10.1039/a907915g

Source and publish data:

Chemical Communications p. 2455 - 2456 (1999)

Update date:2022-08-05

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Authors:

Davies, John E.

Mays, Martin J.

Raithby, Paul R.

Woods, Anthony D.

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Article abstract of DOI:10.1039/a907915g

Deprotonation of the complex [Cp₂(CO)₄Mo₂(μ-PPhH)(μ-H)] by Bu(t)Li at -78 °C and subsequent addition of acryloyl chloride affords the metallophosphaalkene complex [Cp₂(CO)₄Mo₂(η¹

Full text of DOI:10.1039/a907915g

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Product name:Mo₂(CO)4(C₅H₅)2P(C₆H₅)2CHCH₂

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