DARSTELLUNG VON MEHRKERNKOMPLEXEN AUS As2Co2(CO)6

DOI: 10.1016/0022-328X(83)80061-8

Source and publish data:

Journal of Organometallic Chemistry p. 95 - 104 (1983)

Update date:2022-08-03

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Authors:

Mueller, Manfred

Vahrenkamp, Heinrich

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Article abstract of DOI:10.1016/0022-328X(83)80061-8

By reaction of As2Co2(CO)6 with M(CO)5THF (M=Cr, Mo, W), the heteronuclear complexes (CO)5M*As2Co2(CO)6 of low stability were obtained.Phosphine substitution increased the basicity of the As2Co2 cluster, into which up to two PMe3 ligands and up to four P(

Full text of DOI:10.1016/0022-328X(83)80061-8

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