Tetrahedron p. 11793 - 11812 (1998)
Update date:2022-08-02
Topics:
Nielsen, Arnold T.
Chafin, Andrew P.
Christian, Stephen L.
Moore, Donald W.
Nadler, Melvin P.
Nissan, Robin A.
Vanderah, David J.
Gilardi, Richard D.
George, Clifford F.
Flippen-Anderson, Judith L.
Syntheses of new polyazapolycyclic caged polynitramines are described. Sequentially reacting 4,10-dibenzyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12- hexaazaisowurtzitane (5a) with NOBF4 and NO2BF4 in sulfolane solvent produces 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo- [5.5.0.05,9.03,11] dodecane, 6). Syntheses of two new polyazapolycyclic caged trinitramines, 3,5,12-trinitro-3,5,12-triazawurtzitane (7a) and 2,4,10- trinitro-2,4,10-triazaadamantane (12a), as well as their labile parent secondary amines, are discussed. A new caged polynitrosamine, 3,5,12- trinitroso-3,5,12-triazawurtzitane (7d), has been obtained by ring-cleavage nitrosation of the new hexamine-wurtzitane compound 3,5,7,9- tetraazahexacyclo[9.3.1.13,7.02,9.04,13.05,10]-hexadecane (10).
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