STEREOSELECTIVE EPOXIDATION OF ALLYLIC AND HOMOALLYLIC ALCOHOLS WITH 30percent HYDROGEN PEROXIDE CATALYZED BY TUNGSTIC ACID IN BUFFERED MEDIA

DOI: 10.1016/S0040-4039(00)84080-0

Source and publish data:

Tetrahedron Letters p. 711 - 714 (1986)

Update date:2022-07-31

Topics:

Authors:

Prat, Denis

Delpech, Bernard

Lett, Robert

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Article abstract of DOI:10.1016/S0040-4039(00)84080-0

The aqueous tungstic acid-catalyzed hydrogen peroxide epoxidation of allylic alcohols affords the same major diastereoisomer as the VO(acac)2/tBuOOH system with quite comparable stereoselectivities.In contrast, epoxidation of homoallylic alcohols appears to be much less stereoselective.

Full text of DOI:10.1016/S0040-4039(00)84080-0

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