Tetrahedron Letters p. 711 - 714 (1986)
Update date:2022-07-31
Topics:
Prat, Denis
Delpech, Bernard
Lett, Robert
The aqueous tungstic acid-catalyzed hydrogen peroxide epoxidation of allylic alcohols affords the same major diastereoisomer as the VO(acac)2/tBuOOH system with quite comparable stereoselectivities.In contrast, epoxidation of homoallylic alcohols appears to be much less stereoselective.
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