STEREOSELECTIVE EPOXIDATION OF ALLYLIC AND HOMOALLYLIC ALCOHOLS WITH 30percent HYDROGEN PEROXIDE CATALYZED BY TUNGSTIC ACID IN BUFFERED MEDIA

DOI: 10.1016/S0040-4039(00)84080-0

Source and publish data:

Tetrahedron Letters p. 711 - 714 (1986)

Update date:2022-07-31

Topics:

Authors:

Prat, Denis

Delpech, Bernard

Lett, Robert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84080-0

The aqueous tungstic acid-catalyzed hydrogen peroxide epoxidation of allylic alcohols affords the same major diastereoisomer as the VO(acac)2/tBuOOH system with quite comparable stereoselectivities.In contrast, epoxidation of homoallylic alcohols appears to be much less stereoselective.

Full text of DOI:10.1016/S0040-4039(00)84080-0

Products guided by the article

Product name:5-tert-butyl-2,3-epoxy-cyclohexanone

Cas No:26828-85-3

R&D Labs maybe for 26828-85-3

TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Shanghai Xinda Pharmaceuticals Co., Ltd.

Contact:86-21-33692333-8008

Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China
Shanghai Taibao Pharmaceutical Technology Co., Ltd(expird)

Contact:021-52217366

Address:shanghai

Relevant to this article

Epoxide formation by ring closure of the cinnamyloxy radical

Doi:10.1021/ol005749t
(2000)
Lewis Acid-Catalyzed Vinyl Acetal Rearrangement of 4,5-Dihydro-1,3-dioxepines: Stereoselective Synthesis of cis- And trans-2,3-Disubstituted Tetrahydrofurans

Doi:10.1021/acs.joc.0c00390
(2020)
A conjugate vaccine using enantiopure hapten imparts superior nicotine-binding capacity

Doi:10.1021/jm501625j
(2015)
Exchange of dinitrogen between iron and molybdenum centers and the reduction of dinitrogen bound to iron: Implications for the chemistry of nitrogenases

Doi:10.1021/ja00015a050
(1991)
Asymmetric hetero-Diels-Alder reaction of glyoxylate esters and Danishefsky's diene catalyzed by chiral bis(oxazoline)-lanthanide complexes

Doi:10.1016/S0040-4039(00)00144-1
(2000)
Synthesis of 4-cyanophenyl and 4-nitrophenyl 2-azido-2-deoxy-1,5-dithio-β-D-arabino- and -β-D-lyxopyranosides possessing antithrombotic activity

Doi:10.1016/S0008-6215(99)00320-1
(2000)

Article Doi