Chemistry Letters p. 29 - 30 (1995)
Update date:2022-08-04
Topics:
Kyushin, Soichiro
Otani, Shinju
Nakadaira, Yasuhiro
Ohashi, Mamoru
Photoalkylation of tetracyanobenzene and benzil with (n-Bu)3SnSiMe3 or (n-Bu)3SnSn(n-Bu)3 proceeds via electron transfer.In these reactions, the Sn-C bond of (n-Bu)3SnSiMe3 and (n-Bu)3SnSn(n-Bu)3 is cleaved in preference to the Sn-Si and Sn-Sn bonds.Similar cleavage of the Sn-C bond is also observed in mass spectra of these group 14 organometallic compounds.
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