Journal of Organic Chemistry p. 65 - 69 (1983)
Update date:2022-08-02
Topics:
Baumstark, Alfons L.
Vasquez, Pedro C.
The oxidation of sulfides with a series of substituted benzylazobenzene α-hydroperoxides (2a-f) produced the corresponding sulfoxides in good yield (ca. 90 percent) in C6D6 at 34 deg C.The reaction was found to be of the first order with respect to α-azohydroperoxide and to sulfide in aprotic medium.The reaction of BzSPh with acyclic α-azohydroperoxide 2a
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