A NOVEL AMINOMETHYLATION OF SILYL ENOL ETHERS WITH AMINOMETHYL ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE

DOI: 10.1016/S0040-4039(00)86885-9

Source and publish data:

Tetrahedron Letters p. 547 - 550 (1982)

Update date:2022-08-04

Topics:

Authors:

Hosomi, Akira

Iijima, Susumu

Sakurai, Hideki

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Article abstract of DOI:10.1016/S0040-4039(00)86885-9

The iodotrimethylsilane-catalyzed reaction of silyl enol ethers with aminomethyl ethers in acetonitrile gives aminomethylation products of the corresponding ketones readily.The reaction can also be catalyzed by trimethylsilyl trifluoromethanesulfonate in dichloromethane.

Full text of DOI:10.1016/S0040-4039(00)86885-9

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