BIOMIMETIC SYNTHESES OF OPPOSITOL, OPLOPANONE, AND APHANAMOL II FROM GERMACRENE-D

DOI: 10.1016/S0040-4039(00)83939-8

Source and publish data:

Tetrahedron Letters p. 57 - 60 (1986)

Update date:2022-08-05

Topics:

Authors:

Shizuri, Yoshikazu

Shu, Yamaguchi

Terada, Yukimasa

Yamamura, Shosuke

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Article abstract of DOI:10.1016/S0040-4039(00)83939-8

Biomimetic reaction of germacrene-D induced with bromonium ion has been carried out to give several bromo compounds, from which (+/-)-oppositol and (+/-)-oplopanone have been synthesized. (+/-)-Aphanamol II has also been synthesized from epoxygermacrene-D.

Full text of DOI:10.1016/S0040-4039(00)83939-8

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