Hydroxycarbene complexes from paramagnetic acylmetals. Electrochemistry of benzoylchromium(0) and -tungsten(0) carbonyls

DOI: 10.1021/ic50215a009

Source and publish data:

Inorganic Chemistry p. 34 - 40 (1981)

Update date:2022-08-05

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Authors:

Klingler

Huffman Huffman

Kochi Kochi

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Article abstract of DOI:10.1021/ic50215a009

The group 6 acylmetal(0) anions RCOCr(CO)₅^- and RCOW(CO)₅^- yield paramagnetic acylchromium(I) and -tungsten(I) species upon anodic oxidation. Ion-pairing effects with various cations are shown by the shifts of t

Full text of DOI:10.1021/ic50215a009

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