Journal of the Chemical Society. Perkin transactions II p. 1277 - 1280 (1984)
Update date:2022-09-26
Topics:
Nudelman, Sbarbati N.
Palleros, Daniel
The reaction of 2,6-dinitroanisole with cyclohexylamine in methanol and benzene-methanol was studied at several amine concentrations.Althrough the reaction rate in methanol is higher than in benzene, addition of small amounts of methanol to the benzene solution diminishes the rate of reaction (which is of third order in amine), reaching a minimum value at nearly 30percent methanol, after which the rate increases almost linearly with the methanol content.These and other results, here described, are satisfactorily explained by a previously proposed reaction scheme, in which the dimer of the amine is operating.
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