Journal of the Chemical Society. Perkin transactions II p. 1277 - 1280 (1984)
Update date:2022-09-26
Topics:
Nudelman, Sbarbati N.
Palleros, Daniel
The reaction of 2,6-dinitroanisole with cyclohexylamine in methanol and benzene-methanol was studied at several amine concentrations.Althrough the reaction rate in methanol is higher than in benzene, addition of small amounts of methanol to the benzene solution diminishes the rate of reaction (which is of third order in amine), reaching a minimum value at nearly 30percent methanol, after which the rate increases almost linearly with the methanol content.These and other results, here described, are satisfactorily explained by a previously proposed reaction scheme, in which the dimer of the amine is operating.
View MoreHubei New Desheng Technology Co., Ltd
website:http://www.whdsbio.cn
Contact:+86-15071057538
Address:C8-2-2, Optical Valley United Technology City, Gedian Development Zone, Ezhou , City Hubei, China.
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Heading（Nanjing）Pharmtechnologies
Contact:86 25 58467899-950 025-58862846-950
Address:Room C413 Fengyu Building, 115 Fucheng Road, Haidian District, Beijing 100142, China
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
ClickChem Technology Co., Limited
Contact:+86-0310-6519966/0531-52893837
Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Doi:10.1021/ja01319a077
(1934)Doi:10.1021/jm000542r
(2002)Doi:10.1007/s11164-017-3011-7
(2017)Doi:10.1021/jo001615h
(2001)Doi:10.1016/S0022-328X(96)06695-8
(1997)Doi:10.1016/j.tetlet.2019.07.027
(2019)
