First synthesis of a α-trifluoromethyl allenol ether via the Julia-Lythgoe process

DOI: 10.1248/cpb.48.1395

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1395 - 1398 (2000)

Update date:2022-08-05

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Authors:

Yoshimatsu

Hibino Hibino

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Article abstract of DOI:10.1248/cpb.48.1395

α-Trifluoromethyl allenol ethers 9a - e were prepared in moderate to good yields hy the Julia-Lythgoe process using β-ethoxy-β-trifluoromethyl vinylic sulfone 3. Several reactions of 9c were examined to give α,β-unsaturated trifluoromethyl ketone derivatives 11 and 12.

Full text of DOI:10.1248/cpb.48.1395

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