First synthesis of a α-trifluoromethyl allenol ether via the Julia-Lythgoe process

DOI: 10.1248/cpb.48.1395

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1395 - 1398 (2000)

Update date:2022-08-05

Topics:

Authors:

Yoshimatsu

Hibino Hibino

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.48.1395

α-Trifluoromethyl allenol ethers 9a - e were prepared in moderate to good yields hy the Julia-Lythgoe process using β-ethoxy-β-trifluoromethyl vinylic sulfone 3. Several reactions of 9c were examined to give α,β-unsaturated trifluoromethyl ketone derivatives 11 and 12.

Full text of DOI:10.1248/cpb.48.1395

NII-Electronic Library Service

Products guided by the article

Product name:(E)-2-ethoxy-1,1,1-trifluoro-3-(phenylsulfonyl)prop-2-ene

Cas No:303734-12-5

R&D Labs maybe for 303734-12-5

RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Quzhou Aokai Chemical Co., Ltd.

Contact:86-570-3032832

Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
Advanced Biotech

Contact:+1-973-357-0577

Address:10 Taft Rd.
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou

Relevant to this article

A One-Pot Cascade Reaction by Combining NH-Sulfoximines with Thiophenols Under Mild Conditions

Doi:10.1002/ejoc.201701643
(2018)
Doi:10.1016/S0040-4039(00)99732-6
(1970)
Solution-phase preparation of a 560-compound library of individual pure mappicine analogues by fluorous mixture synthesis

Doi:10.1021/ja026947d
(2002)
Investigation of tightly coupled porphyrin arrays comprised of identical monomers for multibit information storage

Doi:10.1021/jo000489e
(2000)
Activation energies for the 1,2-carbon migration of ring-fused cyclopropylchlorocarbenes

Doi:10.1016/j.tetlet.2005.03.209
(2005)
Neighboring-group participation in carbohydrate chemistry. II. Neighboring-group participation of the N,N-diethylamido group in a nucleophilic displacement of a 5-tosylate.

Doi:10.1021/jo00820a030
(1971)

Article Doi