Journal of Fluorine Chemistry p. 377 - 386 (1984)
Update date:2022-07-29
Topics:
Napoli, M.
Fraccaro, C.
Scipioni, A.
Armelli, R.
The preliminary data obtained from thermal decompositions of perfluoro-n-octane-1-sulfonyl fluoride in a continuous tubular-flow reactor are reported.The pyrolysis results in a radical reaction producing fluorocarbons, with high conversions and with yields depending on the experimental conditions.The reaction mixture composition also depends on the experimental conditions, so it is possible to obtain a prevalent formation of either light or heavy fluorocarbons.
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