Preparation and properties of photo-functional systems with nitroxide radicals

Article abstract of DOI:10.1080/10587250108023683

Series of TEMPO-substituted norbornadiene, spiropyran and anthracene derivatives have been prepared; their light-induced structural change to the corresponding qudricyclanes, merocyanines or anthracene-dimers and the reverse reactions to the starting materials have been studied. The antiferromagnetic or ferromagnetic behavior observed in norbornadienes/anthracenes was found to be preserved in the corresponding quadricyclanes/anthracene-dimers in spite of the difference of their Weiss temperatures, whereas switching of the intermolecular magnetic interactions was observed in spiropyran/merocyanine systems.

Full text of DOI:10.1080/10587250108023683

This article was downloaded by: [The University Of Melbourne Libraries]
On: 12 October 2014, At: 04:10
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number:
1072954 Registered office: Mortimer House, 37-41 Mortimer Street,
London W1T 3JH, UK
Molecular Crystals and
Liquid Crystals Science
and Technology. Section A.
Molecular Crystals and Liquid
Crystals
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/gmcl19
Preparation and Properties
of Photo-Functional Systems
with Nitroxide Radicals
Shin'ichi Nakatsuji a , Soichi Takeuchi a , Takeo
Ojima a , Yuya Ogawa a , Hiroki Akutsu a & Jun-
Ichi Yamada a
a Department of Material Science, Faculty of
Science , Himeji Institute of Technology , Kouto
3-2-1, Kamigori, Hyogo, 678-1297, Japan
Published online: 24 Sep 2006.
To cite this article: Shin'ichi Nakatsuji , Soichi Takeuchi , Takeo Ojima , Yuya
Ogawa , Hiroki Akutsu & Jun-Ichi Yamada (2001) Preparation and Properties of
Photo-Functional Systems with Nitroxide Radicals, Molecular Crystals and Liquid
Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals,
356:1, 23-32, DOI: 10.1080/10587250108023683
To link to this article: http://dx.doi.org/10.1080/10587250108023683
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all
the information (the “Content”) contained in the publications on our
platform. However, Taylor & Francis, our agents, and our licensors
make no representations or warranties whatsoever as to the accuracy,

completeness, or suitability for any purpose of the Content. Any opinions
and views expressed in this publication are the opinions and views of
the authors, and are not the views of or endorsed by Taylor & Francis.
The accuracy of the Content should not be relied upon and should be
independently verified with primary sources of information. Taylor and
Francis shall not be liable for any losses, actions, claims, proceedings,
demands, costs, expenses, damages, and other liabilities whatsoever
or howsoever caused arising directly or indirectly in connection with, in
relation to or arising out of the use of the Content.
This article may be used for research, teaching, and private study
purposes. Any substantial or systematic reproduction, redistribution,
reselling, loan, sub-licensing, systematic supply, or distribution in any
form to anyone is expressly forbidden. Terms & Conditions of access
and use can be found at http://www.tandfonline.com/page/terms-and-
conditions