Generation of diazo-2-methylenecyclopropane and its 1,3-dipolar cycloaddition to acrylates

DOI: 10.1007/BF02495762

Source and publish data:

Russian Chemical Bulletin p. 1207 - 1211 (2000)

Update date:2022-08-05

Topics:

Authors:

Tomilov Tomilov

Klimenko

Shulishov

Nefedov Nefedov

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Article abstract of DOI:10.1007/BF02495762

N-(2-Methylenecyclopropyl)-N-nitrosourea (2) was synthesized for the first time (yield 70%) and its decomposition induced by bases was studied. In particular, treatment with MeONa/MeOH at - 30 °C in the presence of methyl methacrylate gives the correspond

Full text of DOI:10.1007/BF02495762

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