Oxovanadium(IV) and niobium(V) complexes with some new Schiff bases

Article abstract of DOI:10.1080/00945710009351854

Complexes of the type [VO(LH)(H₂O)] and [Nb(LH)₂Cl₃], where LH = a singly deprotonated Schiff base derived from condensation of 3-substituted-4-amino-5-mercapto-1,2,4-triazole with benzoin were synthesized in ethanol or dry chloroform, respectively. A coordination number of five for the oxovanadium(IV) and seven for the niobium(V) complexes have been proposed on the basis of analytical, molar conductance, magnetic, IR and ¹H NMR spectral data. Kinetic parameters were established by adopting Broido's method. All of the ligands and their oxovanadium(IV) complexes were screened for their antibacterial, antifungal and antituberculosis activity.

Full text of DOI:10.1080/00945710009351854

This article was downloaded by: [Northeastern University]
On: 21 November 2014, At: 21:05
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsrt19
Oxovanadium(IV) and
Niobium(V) Complexes with
Some New Schiff Bases
G. M. Shashidhara a & T. R. Goudar a
a Department of Chemistry , Karnatak University ,
Dharwad, 580 003, India
Published online: 23 Apr 2008.
To cite this article: G. M. Shashidhara & T. R. Goudar (2000) Oxovanadium(IV)
and Niobium(V) Complexes with Some New Schiff Bases, Synthesis and
Reactivity in Inorganic and Metal-Organic Chemistry, 30:8, 1581-1599, DOI:
10.1080/00945710009351854
To link to this article: http://dx.doi.org/10.1080/00945710009351854
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or

indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions