Supramolecular Chemistry p. 913 - 920 (2016)
Update date:2022-08-04
Topics: Selectivity Sensitivity Water Experimental Cyanide
Wei, Tai-Bao
Cheng, Xiao-Bin
Li, Hui
Lin, Qi
Yao, Hong
Zhang, You-Ming
Taking advantage of the special nucleophilicity of cyanide, a new simple colorimetric chemosensor has been synthesised. This allows a deprotonation reaction to monitoring the cyanide. With the addition of CN? to the chemosensor aqueous solution, which could induce a change in the solution colour from yellowish to deep yellow, while no colour change could be observed in the presence of other hackneyed anions, by which CN? can be distinguished from other anions immediate with the naked eye. At the same time, a fluorescence quenching was implemented upon adding cyanide into the chemosensor aqueous solution. The absorption spectra detection limits of the chemosensor for cyanide was 5.35?×?10?8?M and the fluorescence spectra detection limit was 2.63?×?10?8?M. The cyanide test strips based on the chemosensor could serve as a convenient cyanide test kits. Furthermore, the chemosensor was successfully applied to detect cyanide in sprouting potatoes.
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