A NEW STEREOSELECTIVE SYNTHESIS OF 2-SUBSTITUTED 1,3-BIS(TRIMETHYLSILYL)PROPENE DERIVATIVES AND THEIR CONVERSION TO CYCLOPENTANE AND CYCLOHEXANE DERIVATIVES

DOI: 10.1016/0040-4039(82)80146-9

Source and publish data:

Tetrahedron Letters p. 5419 - 5422 (1982)

Update date:2022-08-04

Topics:

Authors:

Ochiai, Masahito

Sumi, Kenzo

Fujita, Eiichi

Shiro, Motoo

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Article abstract of DOI:10.1016/0040-4039(82)80146-9

Ester 2 on treatment with sodium salt of sulfone or sulfoxide afforded 2-substituted 1,3-bis(trimethylsilyl)propene 3 in good yield, from which cyclopentane and cyclohexane derivatives bearing a trimethylsilyl group in the molecules were synthesized.

Full text of DOI:10.1016/0040-4039(82)80146-9

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