Chemiluminescence of the labile 1,2-dioxetanes and epoxides produced in the oxidation of N-acetylated dihydro- and tetrahydropyrazines by singlet oxygen, dimethyldioxirane, and m-chloroperoxybenzoic acid

DOI: 10.1021/ja00143a011

Source and publish data:

Journal of the American Chemical Society p. 9690 - 9692 (1995)

Update date:2022-08-03

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Authors:

Adam, Waldemar

Ahrweiler, Michael

Vlcek, Pavel

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Article abstract of DOI:10.1021/ja00143a011

The oxidation of the N-acylated pyrazine derivatives 1a,b gave the pyrazine-type dioxetanes 2a,b, which for the first time were isolated and characterized. The halflives of the thermal decomposition of these labile dioxetanes at 20°C were determined by ch

Full text of DOI:10.1021/ja00143a011

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