A Synthetic Study of (-)-Dihydroedulan II and Related Compounds

DOI: 10.1016/S0040-4020(01)89725-8

Source and publish data:

Tetrahedron p. 7227 - 7236 (1991)

Update date:2022-08-05

Topics: Chemical Synthesis Reaction Conditions Analytical Techniques Chemical Reagents Experimental terms Related compounds Synthetic study

Authors:

Sugai, Takeshi

Yokoshi, Tomoki

Watanabe, Naoyuki

Ohta, Hiromichi

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Article abstract of DOI:10.1016/S0040-4020(01)89725-8

(-)-Dihydroedulan II and related compounds were synthesized from (2R,1'RS)-dihydro-α-ionol, which was prepared by lipase-catalyzed enantioselective transesterification of the corresponding diastereomeric mixture as the key-step.Fungal allylic oxidation of (-)-dihydroedulan II worked well to afford a corresponding alcohol as well as (+)-dihydroedulan-8-one.

Full text of DOI:10.1016/S0040-4020(01)89725-8

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