Tetrahedron p. 7227 - 7236 (1991)
Update date:2022-08-05
Topics: Chemical Synthesis Reaction Conditions Analytical Techniques Chemical Reagents Experimental terms Related compounds Synthetic study
Sugai, Takeshi
Yokoshi, Tomoki
Watanabe, Naoyuki
Ohta, Hiromichi
(-)-Dihydroedulan II and related compounds were synthesized from (2R,1'RS)-dihydro-α-ionol, which was prepared by lipase-catalyzed enantioselective transesterification of the corresponding diastereomeric mixture as the key-step.Fungal allylic oxidation of (-)-dihydroedulan II worked well to afford a corresponding alcohol as well as (+)-dihydroedulan-8-one.
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