Electron-transfer reaction of 1,2-disila-3,5-cyclohexadienes

DOI: 10.1016/S0040-4039(97)00693-X

Source and publish data:

Tetrahedron Letters p. 3525 - 3528 (1997)

Update date:2022-08-03

Topics:

Authors:

Kako, Masahiro

Takada, Hideki

Nakadaira, Yasuhiro

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Article abstract of DOI:10.1016/S0040-4039(97)00693-X

Phololysis of 1,2-disila-3,5-cyclohaxadienes 1a-b in the presence of methylene blue as a sensitizer led to efficient formation of the correspondng siloles as ring contraction products. The reaction mechanism is best rationalized by electron-transfer from

Full text of DOI:10.1016/S0040-4039(97)00693-X

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Product name:(3aR,3bR,6aS,6bS)-1,1,6,6-Tetramethyl-2,5,6a,6b-tetraphenyl-1,3a,3b,6,6a,6b-hexahydro-1,6-disila-cyclobutadicyclopentene

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