Tetrahedron Letters p. 3525 - 3528 (1997)
Update date:2022-08-03
Topics:
Kako, Masahiro
Takada, Hideki
Nakadaira, Yasuhiro
Phololysis of 1,2-disila-3,5-cyclohaxadienes 1a-b in the presence of methylene blue as a sensitizer led to efficient formation of the correspondng siloles as ring contraction products. The reaction mechanism is best rationalized by electron-transfer from
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