DIASTEREOSELECTIVITE DANS LA REACTION DES ORGANOMAGNESIENS SUR LE TETRAHYDROFURFURAL ET SON GEM-DIACETATE EN PRESENCE DE HMPT. ACCES AUX DIOLS-1,2 ERYTHRO.

DOI: 10.1016/S0040-4039(86)80041-7

Source and publish data:

Tetrahedron Letters p. 1035 - 1038 (1986)

Update date:2022-08-05

Topics:

Authors:

Amouroux, R.

Ejjiyar, S.

Chastrette, M.

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Article abstract of DOI:10.1016/S0040-4039(86)80041-7

Grignard Reagents - HMPT complexes have been found to be highly stereoselective reagents for the addition to tetrahydrofurfural and for the substitution of an acetoxy group in tetrahydrofurfural gem-diacetate.In both cases, a high erythro/threo ratio was obtained.

Full text of DOI:10.1016/S0040-4039(86)80041-7

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